Chemical labelling information and Safety Data Sheets

Understanding the CLP Labels:

What is CLP? (Classification Labelling Packaging)

The CLP regulations are the EC Regulation No 1272/2008 on Classification,Labelling and Packaging of substances and mixtures. The legislation was introduced throughout the EU as a system to classify and label chemicals based on the United Nations Globally Harmonised System or GHS.

CLP sets detailed criteria for the labelling elements: pictograms, signal words and standard statements for hazard, prevention, response, storage and disposal, for every hazard class and category. It also sets general packaging standards to ensure the safe supply of hazardous substances and mixtures.

Should I be relabelling older CHIP-classified chemicals in the store with the CLP?
YES, the current advice is to put stickers over the old label.

Check the classification and label on the bottle and compare it with what the current Hazcard indicates and add the appropriate CLP pictogram(s) and signal word. In many cases, the hazard classification of a chemical under both CLP and CHIP is very similar.
Full information is provided in the supplied SDS, but we recommend referring to the CLEAPSS Hazcards which offer specific information for school/college use and general guidance on use, storage, emergencies and disposal.

CLP and BREXIT

The UK has left the EU, and the transition period after Brexit comes to an end this year. The European Union (EU) CLP Regulation will be replaced in Great Britain by retained EU law – the GB CLP Regulation. We will give full details once we have more information.

Safe Storage of Chemicals

“It is essential that an up-to-date inventory is kept of all the hazardous chemicals and materials held in school and college stores. Keeping this up-to-date is an effective method of managing hazardous substances and will help reduce any health, safety, and security risk” (DfE Safe storage and disposal of hazardous materials and chemicals Nov 2017).
 
Timstar recommends the Labexpert chemical stock control software.

Use-by or expiry date 

Use-by or expiry date informs users that the stated assay (guarantee of purity) of the (unopened) reagent cannot be relied upon after the stated date.

Concentration expressions

M – molar concentration, molarity is the number of moles of solute (the material dissolved) per litre of solution mol dm-3 or simply M.
N - normality is a measure of concentration equal to the gram equivalent weight per litre of solution.
% - one part in a hundred
v/v – volume by volume, both chemicals in solution are liquids
w/v – weight by volume, solid chemical dissolved in a liquid
w/w – weight by weight, the weight of each chemical is used and not the volume.
Vols. - hydrogen peroxide is given in terms of the volume of oxygen it can produce (100 vol hydrogen peroxide can produce 100 cm3 of oxygen gas).

Useful documents:

• DfE Safe storage and disposal of hazardous materials and chemicals November 2017
• Home Office SYC Secure Your Chemicals Education
• The SYC Assessment Tool

Regulations Table:

Common Name:
A common name is defined by the IUPAC (International Union of Pure and Applied Chemistry) as a name that unambiguously defines a chemical yet does not follow
the current systematic naming convention. An example of a common name is Acetaldehyde, which has the systematic name Ethanal. e.g. Acetaldehyde

Systematic or IUPAC Name:

The systematic name also called the IUPAC name is the preferred way to name a chemical because each systematic name identifies exactly one chemical. The systematic name is determined by guidelines set forth by the IUPAC. e.g. Ethanal

Acetaldehyde LR:

LR - LABORATORY REAGENT: This grade consists of Pure, Extra Pure, Purified, organic and inorganic chemicals having reliable accuracy in routine laboratory analysis.
AR - ANALYTICAL REAGENT: Reagents essential for analytical purpose and research work having high purity.

Assay:

Chemical purity - typically determined from the amount of impurities present. e.g. 98% min

Density: Mass per unit volume: density = mass/volume. e.g. 0.788g/ml

M.W: Molecular weight is the sum of the atomic weight values of the atoms in a molecule. e.g. 44.05

Hazard Statements:

Hazard Statements (H-Statements) are part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). Hazard statements provide standardised wording to indicate the hazards of a product including, when appropriate, the degree of the hazard. e.g. H224, H351, H319, H335.

Precaution Statements:

Precaution Statements (P-Statements) are part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). Precautionary statements provide standardised wording and/or pictograms to describe recommended measures that should be taken to minimise or prevent adverse effects resulting from exposures to a hazardous product, or improper storage, handling, or disposal of a hazardous product.
e.g. P233, P280, P261, P301+P310, P331

Signal Words:

CLP uses a signal word to highlight the danger level. The new signal word has two levels: Danger — those substances and mixtures with the most severe hazards;
Warning — those substances and mixtures with less serious hazards.

Pictograms:

Under CLP, the seven familiar orange squares with symbols have been replaced by nine new red-bordered diamond symbols. Six of these new symbols are very similar, but, as seen below, there are three new or changed ones to become familiar with.

Flash Point

The flashpoint of a chemical is the lowest temperature at which its vapours ignite if given an ignition source. A lower flash point indicates higher flammability.


CHEMICAL SD SHEETS


BROWSE BY PRODUCT CODE

AC1000 Acetaldehyde LR

AC1027 Acetic acid glacial AR

AC1030 Acetic acid 1.0M

AC1038 Acetic anhydride LR

AC1058 Acetyl chloride

AC14005 Acetic acid glacial

AC14015 Acetone

AC14025 Acetone AR

AD1072 Adenosine-5-triphosphoric acid (ATP)

AD1084 Adipoyl chloride in Cyclohexane

AG1092 Agar powder

AG1094 Agar powder

AL1102 Albumen egg powder

AL1114 Aluminium foil 0.1 mm

AL1116 Aluminium powder fine

AL1146 Aluminium chloride 6-water LR

AL1158 Aluminium oxide calcined LR

AL1162 Aluminium potassium sulfate 12-water LR

AL1172 Aluminium sulfate 16-water

AM1186-01 Amino acid set (1)

AM1186-02 Amino acid set (2)

AM1186-03 Amino acid set (3)

AM1186-04 Amino acid set (4)

AM1186-05 Amino acid set (5)

AM1186-06 Amino acid set (6)

AM1186-07 Amino acid set (7)

AM1186-08 Amino acid set (8)

AM1186-09 Amino acid set (9)

AM1186-10 Amino acid set (10)

AM1186-11 Amino acid set (11)

AM1186-12 Amino acid set (12)

AM1186-13 Amino acid set (13)

AM1186-14 Amino acid set (14)

AM1186-15 Amino acid set (15)

AM1186-16 Amino acid set (16)

AM1186-17 Amino acid set (17)

AM1188 Ammonia solution ~33% LR

AM1190 Ammonia solution ~33% LR

AM1222 Ammonium carbonate LR

AM1230 Ammonium chloride LR

AM1246 Ammonium dichromate LR

AM1258 Ammonium oxalate 1-water LR

AM1268 di-Ammonium iron (II) sulfate 6-water LR

AM1271 di-Ammonium iron (II) sulfate 6-water AR

AM1276 Ammonium iron (III) sulfate 12-water

AM1284 Ammonium metavanadate LR

AM1288 Ammonium molybdate (VI) 4-water LR

AM1298 Ammonium nitrate LR

AM1318 Ammonium Thiocyanate LR

AM1338 alpha-Amylase (bacterial source)

AM1340 alpha-Amylase (bacterial source)

AM1342 alpha-Amylase (bacterial source)

AM1344 alpha-Amylase (bacterial source)

AN1394 Anti-bumping granules

AS1426 L-Ascorbic acid

CA1826 Caffeine LR

CA1832 Calcium metal - granular

CA1834 Calcium metal - granular

CA1840 Calcium bromide LR

CA1844 Calcium carbide T

CA1846 Calcium carbonate - precipitated LR

CA1848 Calcium carbonate - precipitated LR

CA1856 Calcium chloride anhydrous - granular LR

CA1868 Calcium chloride 6-Water LR

CA1880 Calcium hydroxide LR

CA1884 Calcium nitrate 4-water LR

CA1892 Calcium oxide - fine powder

CA1906 Calcium sulfate

CA2010 Catechol LR

CE2016 Mineral wool

CH2038 Charcoal powder - activated

CH2042 Charcoal wood powder

CH2052 Chlorine water

CH2064 2-Chlorobutane LR

CH2068 Chloroform LR

CH2080 2-Chloro-2-methylpropane

CH2100 Chromium (III) chloride 6-water LR

CH2110 Chromium (III) potassium sulfate 12-water LR

CH2118 Chromium (III) sulfate basic LR

CI2126 Cinnamic acid LR

CI2130 Citric acid monohydrate LR

CI2132 Citric acid monohydrate LR

CI2135 Citric acid monohydrate AR

CI2140 Citric acid - anhydrous LR

CM68260 Macconkey's Agar

CM68460 Malt Extract Agar

CM68462 Malt Extract Agar

CM68490 MRS Agar

CM68500 Nutrient Agar

CM68520 Nutrient Agar

CM68590 Nutrient Broth

CM68595 Nutrient Broth

CO17010 Copper metal powder

CO2158 Cobalt (II) chloride 6-water LR

CO2160 Cobalt (II) chloride 6-water LR

CO2190 Copper foil 0.1mm - Technical grade

CO2192 Copper foil 0.1mm - Bright finish

CO2198 Copper powder - fine

CO2204 Copper millings

CO2208 Copper (I) chloride LR

CO2216 Copper (I) oxide LR

CO2224 Copper (II) carbonate basic

CO2226 Copper (II) carbonate basic

CO2228 Copper (II) carbonate basic

CO2230 Copper (II) chloride 2-water LR

CO2240 Copper (II) nitrate 3-water LR

CO2250 Copper (II) oxide - powder LR

CO2252 Copper (II) oxide - powder LR

CO2255 Copper (II) oxide - powder AR

CO2260 Copper (II) sulfate 5-water LR

CO2262 Copper (II) sulfate 5-water LR

CO2266 Copper (II) sulfate 5-water LR

CO2271 Copper (II) sulfate 5-water -AR

CO2276 Copper (II) sulfate - anhydrous LR

CR2314 Cresol red indicator

CR2318 Cresol red 0.02% aqueous solution (Indicator)

CR2328 Crystal violet aqueous solution (1%)

CY14005 Cyclohexane LR

CY2332 Cyclohexane LR

CY2340 Cyclohexanol LR

CY2350 Cyclohexene LR

PA4446 Palmitic acid LR

PA4450 Pancreatin from pig pancreas

PA4452 Paraffin liquid - light LR

PA4454 Paraffin liquid - light LR

PA4476 Paraffin wax 56-58°C

PE14005 petroleum spirit 40/60

PE14010 petroleum spirit 60/80

PE14015 petroleum spirit 80/100

PE14020 petroleum spirit 100/120

PE4494 n-Pentane LR

PE4502 Pentan-1-ol LR

PE4506 Pepsin powder

PE4524 Petroleum jelly - white

PE4528 Petroleum ether 40-60°C

PE4532 Petroleum ether 60-80°C

PE4536 Petroleum ether 80-100°C

PE4540 Petroleum ether 100-120°C

PH4548 Ferroin indicator solution

PH4550 Phenol, crystals LR

PH4566 Phenolphthalein (pH indicator)

PH4574 Phenolphthalein 1% solution

PH4582 Phenol Red 0.02% indicator solution

PH4600 Phenyl salicylate LR

PH4602 Phenyl salicylate LR

PH4632 Phosphoric acid

PL4792 Platinum, wire 0.25mm dia

PO4808 Potassium metal (in Liquid paraffin)

PO4810 Potassium metal (in Liquid paraffin)

PO4818 Potassium bromate (V) LR

PO4824 Potassium bromide LR

PO4834 Potassium carbonate anyhydrous LR

PO4840 Potassium chlorate (V) LR

PO4852 Potassium chloride LR

PO4855 Potassium chloride AR

PO4856 Potassium chromate (VI) LR

PO4868 Potassium dichromate (VI) LR

PO4882 Potassium dihydrogen phosphate (V) LR

PO4892 Potassium ferricyanide LR

PO4900 Potassium ferrocyanide

PO4918 Potassium hydrogen carbonate LR

PO4928 di-Potassium hydrogen phosphate

PO4930 Potassium hydrogen phthalate LR

PO4932 Potassium hydrogen phthalate LR

PO4933 Potassium hydrogen phthalate AR

PO4948 Potassium hydroxide, pellets LR

PO4953 Potassium hydroxide, pellets AR

PO4960 Potassium iodate (V) LR

PO4963 Potassium iodate (V) AR

PO4974 Potassium iodate (VII)

PO4976 Potassium iodide LR

PO4978 Potassium iodide LR

PO4981 Potassium iodide AR

PO4983 Potassium iodide AR

PO4988 Potassium permanganate LR

PO4998 Potassium permanganate 0.2M (1.0N) std. solution

PO5000 Potassium permanganate 0.02M (0.1N) std. solution

PO5012 Potassium nitrate LR

PO5018 Potassium nitrate LR

PO5022 Potassium oxalate 1-water LR

PO5032 Potassium persulfate LR

PO5036 Potassium sodium (+) tartrate LR

PO5042 Potassium sulfate LR

PO5060 Potassium thiocyanate LR

PO5062 Potassium thiocyanate LR

PR14005 Propan-2-OL pure 1L

PR14010 propan-2-ol

PR14015 propan-1-ol

PR5088 Propan-1-ol LR

PR5094 Propan-2-ol LR

PR5102 Propionaldehyde LR

PR5104 Propionaldehyde LR

PR5106 Propionic Acid LR

PV13005 Polyvinyl Alcohol

SA5250 Safranin O Stain C.I.50240

SA5266 Salicylic acid LR

SA5278 Sand - Fine White

SE5300 Sebacoyl chloride LR

SE5306 Sebacoyl chloride 5% in Cyclohexane

SI5332 Silica gel (1-3mm)

SI5336 Silica gel self-indicating (1-3mm)

SI5338 Silica gel self-indicating (1-3mm)

SI5340 Silica gel chromatographic

SI5364 Silver wire

SI5370 Silver nitrate LR

SI5372 Silver nitrate LR

SI5374 Silver nitrate LR

SI5377 Silver nitrate AR

SI5382 Silver nitrate 0.1M (0.1N) Solution

SI5386 Silver nitrate 0.1M (0.1N) Solution

SO14005 Sodium hydroxide pearl

SO5412 Soda Lime, granulated 'Carbosorb'

SO5416 Soda Lime, self Indicating 'Carbosorb'

SO5422 Sodium metal (in Liquid Paraffin)

SO5436 Sodium acetate 3-Water LR

SO5444 Sodium acetate Anhydrous LR

SO5450 Sodium alginate

SO5470 Sodium bromide LR

SO5480 Sodium carbonate anhydrous LR

SO5482 Sodium carbonate anhydrous LR

SO5487 Sodium carbonate anhydrous AR

SO5490 Sodium carbonate 10-Water

SO5494 Sodium carbonate 10-Water

SO5520 Sodium chlorate (V) LR

SO5524 Sodium chloride - Granular T

SO5528 Sodium chloride L

SO5530 Sodium chloride L

SO5532 Sodium chloride L

SO5544 Sodium chloride Technical

SO5550 tri-Sodium citrate 2-Water LR

SO5564 Sodium dichromate (VI) Anhydrous LR

SO5566 Sodium dihydrogen phosphate (V) 2-Water LR

SO5590 Sodium oxalate

SO5606 Sodium formate LR

SO5610 Sodium hydrogen carbonate LR

SO5612 Sodium hydrogen carbonate LR

SO5615 Sodium hydrogen carbonate AR

SO5626 di-Sodium hydrogen phosphate 12-Water LR

SO5634 Sodium hydrogen sulfate

SO5642 Sodium hydroxide, pearl

SO5646 Sodium hydroxide pearl

SO5656 Sodium hydroxide, pellets LR

SO5658 Sodium hydroxide, pellets LR

SO5663 Sodium hydroxide pellets AR

SO5672 Sodium hydroxide 2.0M (2.0N) Std. Solution

SO5678 Sodium hydroxide 1.0M (1.0N)

SO5680 Sodium hydroxide 1.0M (1.0N)

SO5684 Sodium hydroxide 0.1M (0.1N) Std. Solution

SO5686 Sodium hydroxide 0.1M (0.1N) Std. Solution

SO5692 Sodium hydroxide 1.0M (1.0N) CVS

SO5696 Sodium hydroxide 0.1M (0.1N) CVS

SO5698 Sodium hypochlorite Solution

SO5700 Sodium hypochlorite Solution

SO5708 Sodium iodide LR

p>

SO5716 Sodium metabisulphite LR

SO5732 Sodium nitrate LR

SO5768 Sodium persulfate LR

SO5792 Sodium silicate solution

SO5812 Sodium sulfate anhydrous LR

SO5862 Sodium thiosulfate 5-water LR

SO5864 Sodium thiosulfate 5-water LR

SO5867 Sodium thiosulfate 5-water AR

SO5872 Sodium thiosulfate anhydrous LR

ST5936 Starch - soluble LR

ST5941 Starch - soluble AR

ST5928  Starch from potato LR

ST5952  Stearic acid

ST5960  Strontium chloride LR

ST5968  Strontium nitrate, anhydrous LR

SU5996 Sucrose LR

SU5998 Sucrose LR

SU6001 Sucrose AR

SU6008 Sudan (III) C.I.26100

SU6014 Sudan III solution, Alcoholic solution 0.5%

SU6040 Sulfur fine powder

SU6112 Sulfuric acid 0.5M (1.0N) Std. Solution

SU6106 Sulfuric acid 1M (2.0N) Std. Solution

SU6102 Sulfuric acid 2M (4.0N) Std. Solution

SU18001 Sulphuric Acid 96 % AR

SU6077 Sulfuric acid 98% AR

SU8000 Superwool 607